화학공학소재연구정보센터
Materials Chemistry and Physics, Vol.120, No.2-3, 244-250, 2010
Structure, morphology and mechanical properties of electrodeposited composite coatings Ni-P/SiC
Physical properties of the NiP/SiC deposits are discussed according to the electroplating parameters and heat treatments. The insertion of silicon carbide in the coatings does not modify their rigidity (E=230 GPa), increases their hardness slightly (50 Vickers) and decreases the residual stresses in the coatings. The phosphorus content has a major effect on the structure and the physical properties. Indeed, the insertion of phosphorus into the deposits generates a grain size reduction or even an amorphisation which results in morphological modifications observed by AFM. In parallel a very important hardening is associated with incorporation of phosphorus: hardness is multiplied by 3 to reach 600 HV0.1. The deposits tend to become crystalline following the heat treatments. With 420 degrees C, the precipitation of a Ni3P phase which distorts the crystal lattice is observed, increasing the hardness of the deposits. (c) 2009 Elsevier B.V. All rights reserved.