Investigations of obtaining BiSb, BiTe, SbTe and BiSbTe films in concentrated chloride aqueous solution (5M NaCl + 1 M HCl) or in ionic liquid based on choline chloride + malonic acid mixture were reported. The concentrations of Bi, Sb, Te, existing as complex anions due to high Cl- concentration, were within 10-90 mM. The measurements were carried out at room temperature for aqueous medium and 85 degrees C for ionic liquid. Cyclic voltammetry and electrochemical impedance spectroscopy using Pt electrode were used for investigating the interface process in both electrolytes. The morphology and chemical composition of films deposited on Cu in chloride aqueous solution using current pulses or potential pulses were determined by AFM and SEM microscopy. For BiSb, the effects of change from unipolar to reverse pulses and increase in cathodic current were shown as favorable. SEM images for BiSbTe confirmed the morphology modification by increasing the current pulses, while energy dispersive spectroscopy analyses indicate a dramatic change of composition. (C) 2010 Elsevier B.V. All rights reserved.