The aim of this paper is to develop a macroscopic model for the transport of a passive solute, by diffusion and convection, in a heterogeneous medium consisting of impervious solids periodically distributed in a porous matrix. In the porous part, the flow is described by Darcy's law. Attempt is made to derive the macroscopic equation governing the average concentration field in the equivalent macroscopic medium and the macroscopic transport parameters. The analysis is conducted in the case when convection and diffusion are of the same order of magnitude at the macroscopic level, that is, when the Peclet number is of order 1. The proposed macroscopic model is obtained using the homogenization method for periodic structures with a double scale asymptotic expansion, in which the small parameter e is the ratio between the two characteristic lengths l (the period scale of the impervious bodies distribution) and L (the scale of the macroscopic sample). The macroscopic parameters, which characterize the multiporous medium, depend solely on the transport parameters in the porous matrix and on the geometry of the impervious inclusions without any phenomenological assumption. Numerical computations are performed using a finite element method for several geometries of the solid inclusions, in two- and three-dimensional cases.