화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Macromolecular Research, Vol.19, No.3, 250-260, March, 2011
DOI10.1007/s13233-011-0311-4  Export Citation
Silica/Polyimide-Polydimethylsiloxane Hybrid Films. Thermal and Electrical Properties
Corneliu Hamciuc†, Elena Hamciuc, and Lidia Okrasa1
  • “Petru Poni” Institute of Macromolecular Chemistry, Aleea Gr. Ghica Voda 41A, Iasi, 700487, Romania
  • 1Department of Molecular Physics, Technical University of Lodz, Zeromskiego 116, 90-924, Lodz, Poland, Korea
E-mail:
Hybrid films containing silica were prepared using a poly(amic acid) incorporating polydimethylsiloxane segments and tetraethoxysilane via a sol-gel technique and thermal cyclodehydration. The surface morphology of the films was examined by atomic force microscopy and scanning electron microscopy. The free surface energy was evaluated based on contact angle measurements. The films were flexible and showed good mechanical properties. They exhibited high thermal stability with an initial decomposition temperature above 420℃ and a glass transition temperature in the range of 216-223 ℃. Dielectric spectroscopy revealed primary α1 relaxation due to the polydimethylsiloxane segments, and three subglass transitions: γ, β1 and β2. At higher temperatures, α2-relaxation that corresponds to the upper glass transition and a conductivity process appeared. The influence of the silica content on the hybrid film properties was examined. Dynamic mechanical analysis revealed similar relaxation processes to those observed by dielectric spectroscopy.
Keywords:hybrid film;silica;polyimide-polydimethylsiloxane;thermal stability;dielectric spectroscopy.
  1. Ghosh MK, Mittal KL, Eds., Polyimides: Fundamentals and Applications, Marcel Dekker, New York, 1996.
  2. Sato M, in Handbook of Thermoplastics, Olabisi O, Ed., Marcel Dekker, New York, 1997, pp 665-699.
  3. Wilson D, Stenzenberger HD, Hergenrother PM, Eds., Polyimides, Chapman and Hall, New York, 1990.
  4. Ghosh A, Banerjee S, Polym. Adv. Technol., 19, 1486 (2008)
  5. Jones RG, Ando N, Chojnowski J, Eds., Silicon-Containing Polymers. The science and technology of their synthesis and applications, Kluwer Academic Publisher, Dordrecht, 2000.
  6. Zielecka M, Kozakiewicz J, Przbylski J, Sobczak J, Surf. Coat. Int., Part B: Coat. Trans., 85, 215 (2002)
  7. McGrath JE, Dunson DL, Hedrick JL, Adv. Polym. Sci., 140, 62 (1999)
  8. Hamciuc E, Hamciuc C, Cazacu M, Lisa G, Okrasa L, J. Macromol. Sci.-Pure Appl. Chem., 44, 1069 (2007)
  9. Hamciuc C, Hamciuc E, Cazacu M, Okrasa L, Polym. Bull., 59(6), 825 (2008)
  10. Ghosh A, Banerjee S, J. Appl. Polym. Sci., 109(4), 2329 (2008)
  11. Hamciuc E, Hamciuc C, Cazacu M, Ignat M, Zarnescu G, Eur. Polym. J., 45, 182 (2009)
  12. Ghosh A, Banerjee S, Komber H, Schneider K, Haußler L, Voit B, Eur. Polym. J., 45, 1561 (2009)
  13. Novak I, Sysel P, Zemek J, Spirkova M, Velic D, Aranyosiova M, Florian S, Pollak V, Kleinova A, Lednicky F, Janigova I, Eur. Polym. J., 45, 57 (2009)
  14. Kramarenko VY, Shantalil TA, Karpova IL, Dragan KS, Privalko EG, Privalko VP, Fragiadakis D, Pissis P, Polym. Adv. Technol., 15, 144 (2004)
  15. Chen BK, Chiu TM, Tsay SY, J. Appl. Polym. Sci., 94(1), 382 (2004)
  16. Al-Kandary S, Ali AAM, Ahmad Z, J. Appl. Polym. Sci., 98(6), 2521 (2005)
  17. Jiang LZ, Wang WC, Wei XW, Wu DZ, Jin RG, J. Appl. Polym. Sci., 104(3), 1579 (2007)
  18. Foroutan M, Khoee S, J. Appl. Polym. Sci., 104(5), 3228 (2007)
  19. Liu W, Zhu B, Zhang J, Xu YY, Polym. Adv. Technol., 18, 522 (2007)
  20. Qin JQ, Zhao H, Liu XY, Zhang XY, Gu Y, Polymer, 48(12), 3379 (2007)
  21. Chiang TH, Liu SL, Lee SY, Hsieh TE, Eur. Polym. J., 44, 3482 (2008)
  22. Chen S, Shen D, Zhu X, Tian X, Zhou D, Fan L, Eur. Polym. J., 45, 2767 (2009)
  23. Son M, Ha Y, Choi MC, Lee T, Han D, Han S, Ha CS, Eur. Polym. J., 44, 2236 (2008)
  24. Khalil M, Saeed S, Ahmad Z, J. Appl. Polym. Sci., 107(2), 1257 (2008)
  25. Park HB, Kim JH, Kim JK, Lee YM, Macromol. Rapid Commun., 23(9), 544 (2002)
  26. Park HB, Kim JK, Nam SY, Lee YM, J. Membr. Sci., 220(1-2), 59 (2003)
  27. Hamciuc E, Hamciuc C, Ignat M, High Perform. Polym., 22, 225 (2010)
  28. Musto P, Abbate M, Lavorgna M, Ragosta G, Scarinzi G, Polymer, 47(17), 6172 (2006)
  29. Hamciuc E, Hamciuc C, Olariu M, Polym. Eng. Sci., 50(3), 520 (2010)
  30. Hamciuc E, Hamciuc C, Olariu M, Ciobanu R, Polym. Int., 59, 668 (2010)
  31. Fragiadakis D, Logakis E, Pissis P, Kramarenko VY, Shantalii TA, Karpova IL, Dragan KS, Privalko EG, Usenko AA, Privalko VP, J. Phys. Conference Series, 10, 139 (2005)
  32. Cazacu M, Vlad A, Simionescu M, Racles C, Marcu M, J. Macromol. Sci.-Pure Appl. Chem., 39, 1487 (2002)
  33. Owens DK, Wendt RC, J. Appl. Polym. Sci., 13, 1741 (1969)
  34. Cornelius CJ, Marand E, Polymer, 43(8), 2385 (2002)
  35. Habas JP, Peyrelasse J, Grenier-Loustalotz MF, High Perform. Polym., 8, 515 (1996)
  36. Lee HT, Chuang KR, Chen SA, Wei PK, Hsu JH, Fann WS, Macromolecules, 28(23), 7645 (1995)
  37. Sun ZH, Dong LS, Zhuang YG, Cao LY, Ding MX, Feng ZL, Polymer, 33, 4728 (1992)
  38. Pietrasik J, Gaca M, Zaborski M, Okrasa L, Boiteaux G, Gain O, Eur. Polym. J., 45, 3317 (2009)