화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Macromolecular Research, Vol.19, No.9, 965-971, September, 2011
DOI10.1007/s13233-011-0910-0  Export Citation
Synthesis and Characterization of Blue Light Emitting Polymers Based on Arylene Vinylene
Hyuntae Park, Dong-Cheol Shin1, Sung-Chul Shin, Jin-Hak Kim2, Soon-Ki Kwon2, †, and Yun Hi Kim†
  • Department of Chemistry and Research Institute of Natural Science, Gyeongsang National University, Gyeongnam, 660-701, Korea
  • 1Corporate R&D center, SK Energy, Daejeon, 305-712, Korea
  • 2School of Materials Science & Engineering and Engineering Research Institute, Gyeongsang National University, Gyeongnam, 660-701, Korea
E-mail:,
New blue polymers having poly(arylenevinylene) derivatives composed of biphenylene-vinylene-m-(tbutylated) phenylene-vinylene and terphenylene-vinylene-m-(t-butylated)phenylene-vinylene in the main chain were synthesized by nickel catalyzed Yamamoto coupling and palladium-catalyzed Suzuki coupling reactions. The polymers showed good solubility in a common organic solvent and weight average molecular weights of 11,100 to 9,800 with a polydispersity index of 1.46-1.2. The polymers with a highly twisted structure exhibited deep blue emission with (λmax=465 for the homopolymer and λmax=457 nm for copolymer) as well as good thermal stability. Double layer light emitting diode devices fabricated using the obtained polymers as emitters showed blue emission with a maximum brightness of 18-225 cd/m2.
Keywords:light emitting polymer;blue emission;arylene vinylene;highly twisted structure.
  1. Burroughes JH, Bradley DDC, Brown AR, Marks RN, Mackay K, Friend RH, Burn PL, Holmes AB, Nature, 347, 539 (1990)
  2. Braun D, Heeger A, J. Appl. Phys. Lett., 58, 1982 (1991)
  3. Lee SK, Ahn T, Cho NS, Lee JI, Jung YK, Lee J, Shim HK, J. Polym. Sci. A: Polym. Chem., 45(7), 1199 (2007)
  4. Jeong E, Kim SH, Jung IH, Xia Y, Lee K, Suh H, Shim HK, Woo HY, J. Polym. Sci. A: Polym. Chem., 47(14), 3467 (2009)
  5. Song S, Jin Y, Kim SH, Shim JY, Son S, Kim I, Lee K, Suh H, J. Polym. Sci. A: Polym. Chem., 47(23), 6540 (2009)
  6. Liu J, Cheng YX, Xie ZY, Geng YH, Wang LX, Jing XB, Wang FS, Adv. Mater., 20(7), 1357 (2008)
  7. Liang Q, Zhao P, Woo JW, Park YS, Niu LH, Zhang FS, Macromol. Res., 18(2), 113 (2010)
  8. Lee KS, Kim YH, Lee Y, Jang J, Kwon SK, J. Polym. Sci. A: Polym. Chem., 43(11), 2316 (2005)
  9. Kim SO, Jung HC, Lee MJ, Kim YH, Kwon SK, J. Polym. Sci. A: Polym. Chem., 21, 5908 (2009)
  10. Luo J, Li XZ, Hou Q, Peng JB, Yang W, Cao Y, Adv. Mater., 19(8), 1113 (2007)
  11. Chen HY, Chen CT, Chen CT, Macromolecules, 43(8), 3613 (2010)
  12. Jin JK, Kwon SK, Kim YH, Shin DC, You H, Jung HT, Macromolecules, 42(17), 6339 (2009)
  13. Park JW, Park SJ, Kim YH, Shin DC, You H, Kwon SK, Polymer, 50(1), 102 (2009)
  14. Klaerner G, Miller RD, Macromolecules, 31(6), 2007 (1998)
  15. Jing WX, Craft A, Moratt SC, Gruner J, Cacialli F, Hamer PJ, Holmes AB, Friend RH, Synth. Met., 67, 161 (1994)
  16. Liao L, Cirpan A, Ding LM, Karasz FE, Pang Y, J. Polym. Sci. A: Polym. Chem., 44(7), 2307 (2006)
  17. Tang R, Chuai Y, Cheng C, Xi F, Zou DJ, J. Polym. Sci. A: Polym. Chem., 43, 3126 (2006)
  18. Lee NHS, Chen ZK, Huang W, Xu YS, Cao Y, J. Polym. Sci. A: Polym. Chem., 42(7), 1647 (2004)
  19. Kim YH, Park JC, Kang HJ, Park JW, Kim HS, Kim JH, Kwon SK, Macromol. Res., 13(5), 403 (2005)
  20. Kim JS, Heo J, Kang P, Kim JH, Jung SO, Kwon SK, Kim UK, Kim YH, Macromol. Res., 17(2), 91 (2009)
  21. Gren G, Paar C, Stampl J, Leising G, Chem. Mater., 7, 2 (1995)
  22. Chen SA, Chao CI, Synth. Met., 79, 93 (1996)
  23. An BK, Kim YH, Shin DC, Park SY, Yu HS, Kwon SK, Macromolecules, 34(12), 3993 (2001)
  24. Kim YH, Jung SY, Jung SO, Park MH, Kwon SK, J. Polym. Sci. A: Polym. Chem., 4, 4923 (2006)
  25. Kim YH, Shin DC, Kwon SK, Lee JH, J. Mater. Chem., 12, 1280 (2002)
  26. Kim YH, Ahn JH, Shin DC, Kim HS, Kwon SK, Opt. Mater., 21, 175 (2002)
  27. Kim YH, Shin DC, Kwon SK, Polymer, 46(13), 4647 (2005)
  28. Kim YH, Ahn JH, Shin DC, Kwon SK, Polymer, 45(8), 2525 (2004)