화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Polymer(Korea), Vol.35, No.5, 409-418, September, 2011
Export Citation
비닐단량체를 함유한 새로운 실리콘의 합성과 수성 Polyurethane-Veova/Vinyl Acetate 하이브리드 에멀젼 공중합체 내에서 사용
Synthesis of Novel Silicone Containing Vinylic Monomer and Its Uses in the Waterborne Polyurethane-Veova/Vinyl Acetate Hybrid Emulsion Copolymers
Hamid Javaherian Naghash†, and Elham Kasaeian Naeni
  • Department of Chemistry, Islamic Azad University, Shahreza Branch, P.O. Box 311-86145, Shahreza, Isfahan, I. R. Iran
E-mail:
A novel silicone (Si) containing vinylic monomer, N-(3-(triethoxysilyl)propyl) methacrylamide (TESPMA), based on 3-aminopropyltriethoxysilane (APTES) and methacryloyl chloride (MCl) has been synthesized for formulation of waterborne polyurethane (WPU). Two types of vinyl group containing Si, methacryloxypropyltriethoxysilane (MPTES) and triethoxyvinylsilane(TEVS), have been used as coupling reagents for comparison of the effects of Si kinds with TESPMA on the WPU. A series of new siliconized WPU, vinyl acetate/vinyl ester of versatic acid (VAc-Veova), TESPMA, MPTES and TEVS hybrid latexes have been successfully prepared by emulsion polymerization in the presence of WPU dispersion.
Keywords:N-(3-(triethoxysilyl)propyl) methacrylamide;silicones;polyurethanes;polymer synthesis and characterization;glass transition;coatings.
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