항균성과 난연성을 함유하고 있는 인계고분자 코팅용액의 합성

김상겸; 이인수; 서상희; 최성호; Sang-Kyum Kim; In-Soo Lee; Sang-Hee Seo; Seong-Ho Choi

Polymer(Korea), Vol.35, No.5, 431-437, September, 2011

Export Citation

항균성과 난연성을 함유하고 있는 인계고분자 코팅용액의 합성

Synthesis of Phosphoric Polymer Coating Solution with Antimicrobial Activity and Flame Retardant Efficiency

김상겸, 이인수¹, 서상희², 최성호^†

한남대학교 화학과
¹한남대학교 생명공학과
²충남대학교 수의학과

Sang-Kyum Kim, In-Soo Lee¹, Sang-Hee Seo², and Seong-Ho Choi^†

Department of Chemistry, Hannam University, Daejeon 305-811, Korea
¹Department of Biotechnology, Hannam University, Daejeon 305-811, Korea
²Department of Veterinary Medicine, Chungnam National University, Daejeon 305-764, Korea

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초록

아크릴계 이중인산과 과황산암모늄을 개시제로 사용하여 고분자 코팅용액의 기반인 poly(acryloyl diphosphoric acid)(poly(ADP))를 70 ℃의 수용액에서 라디칼 중합반응으로 제조하였다. 제조된 고분자 코팅용액인 poly(ADP)는 salmonella typhimurium, pseudomonas aeruginosa, escherichia coli, 그리고 staphylococcus aureus에 대한 항균성을 보였으며, 또한, Asperigillus niger와 조류인플루엔자 바이러스인 H1N1 바이러스에 대해서도 좋은 항진균성을 보여주었다. 더욱이 면섬유에 제조된 코팅용액 poly(ADP)를 코팅시켰을 경우에 우수한 난연성을 보여주었다.

A polymeric coating solution based on poly(acryloyl diphosphoric acid)(poly(ADP)) was prepared via a radical polymerization of acryloyl diphosphoric acid using ammonium persulfate (APS) as an initiator in water at 70 ℃. The prepared polymeric coating solution exhibited significant antibacterial activity against salmonella typhimurium, pseudomonas aeruginosa, escherichia coli, and staphylococcus aureus. It also exhibited good antifungal activity against Asperigillus niger and good antiviral activity against the influenza (H1N1) virus. Additionally, it exhibited good flame retardant efficiency after applying it as a coating to a cotton fabric.

Keywords:polymeric coating solution;antibacterial activity;antifungal activity;antivirus activity;flame retardant efficiency.

[References]

Bang MS, Korea Patent 1009778590000 (2010)
Hong SC, Korea Patent 1002629810000 (2010)
Kim JN, Park JY, Korea Patent 1020100077964 (2008)
Yang DM, Korea Patent 1008254340000 (2008)
Kenawy FI, Abdel-Hay F, El-Raheem A, El-Shanshoury R, El-Newehy H, J. Control. Release., 50, 145 (1998)
Miyamoto K, Korea Patent 1005097900000 (2005)
Lee JH, Kim SM, Korea Patent 1020090131847 (2009)
Moon WS, Kim JC, Jung KH, Kong KO, Hwang JH, Korea Patent 1005365510000 (2005)
Lee IJ, Kim SW, Korea Patent 1020010016825 (2001)
Yunjian D, Yuqiao Z, Shuchao D, Bao Y, Innov. Food Sci. Emer. Technol., 10, 103 (2009)
Dutta PK, Tripathi S, Mehrotra GK, Dutta J, Food Chemistry., 114, 1173 (2009)
Guiqian L, Dingcai W, Ruowen F, Polymer., 67, 355 (2007)
Terence JP, Carbohyd. Polym., 36, 335 (1998)
Kenawy ER, Worley SD, Broughton R, Biomacromolecules, 8(5), 1359 (2007)
Chena L, Wang YZ, Polymer. Adv. Technol., 21, 1 (2010)
Sheng Z, Horrocks AR, Prog. Polym. Sci., 28, 1517 (2003)
Sakai S, Watanabe J, Honda Y, Takatsuki H, Aoki I, Futamatsu M, Shiozakic K, Chemosphere., 42, 519 (2001)
Wooley WD, Fardell PJ, Fire Safety Journal., 5, 29 (1982)
Baek HD, Seo SH, Korea Patent 1020100052656 (2010)
Kang YM, Song BM, Lee JS, Kim HS, Seo SH, Arch Virol, DOI 10.1007/s00705-010-0914-7 (2011)
Russel AD, Hugo WB, Ayliffe GAJ, Principles and Practice of Disinfection, Preservation and Sterilization, 3rd ed., Oxford, Blackwell Science Ltd., pp124-148 (1999)
Arias-Moliz MT, Ferrer-Luque CM, Espigares-Rodriguez E, Liebana-Urena J, Espigares-Garcia M, OOOOE (Oral Surg Oral Med Oral Pathol Oral Radiol Endod)., 106, 84 (2008)
Lee SM, Lee BS, T. Byun TG, Song, KC, Colloid Surface A., 355, 167 (2010)
Tan SZ, Ding LC, Liu YL, Ouyang YS, Chen YB, Chin. Chem. Lett., 18, 85 (2007)
Bryaskova R, Pencheva D, Kale GM, Lad U, Kantardjiev T, J. Colloid Interface Sci., 349(1), 77 (2010)
Hwang TS, Lee BJ, Yang YK, Choi JH, Kim HJ, Prospect. Ind. Chem., 8(6), 36 (2005)

[1] Bang MS, Korea Patent 1009778590000 (2010)

[2] Hong SC, Korea Patent 1002629810000 (2010)

[3] Kim JN, Park JY, Korea Patent 1020100077964 (2008)

[4] Yang DM, Korea Patent 1008254340000 (2008)

[5] Kenawy FI, Abdel-Hay F, El-Raheem A, El-Shanshoury R, El-Newehy H, J. Control. Release., 50, 145 (1998)

[6] Miyamoto K, Korea Patent 1005097900000 (2005)

[7] Lee JH, Kim SM, Korea Patent 1020090131847 (2009)

[8] Moon WS, Kim JC, Jung KH, Kong KO, Hwang JH, Korea Patent 1005365510000 (2005)

[9] Lee IJ, Kim SW, Korea Patent 1020010016825 (2001)

[10] Yunjian D, Yuqiao Z, Shuchao D, Bao Y, Innov. Food Sci. Emer. Technol., 10, 103 (2009)

[11] Dutta PK, Tripathi S, Mehrotra GK, Dutta J, Food Chemistry., 114, 1173 (2009)

[12] Guiqian L, Dingcai W, Ruowen F, Polymer., 67, 355 (2007)

[13] Terence JP, Carbohyd. Polym., 36, 335 (1998)

[14] Kenawy ER, Worley SD, Broughton R, Biomacromolecules, 8(5), 1359 (2007)

[15] Chena L, Wang YZ, Polymer. Adv. Technol., 21, 1 (2010)

[16] Sheng Z, Horrocks AR, Prog. Polym. Sci., 28, 1517 (2003)

[17] Sakai S, Watanabe J, Honda Y, Takatsuki H, Aoki I, Futamatsu M, Shiozakic K, Chemosphere., 42, 519 (2001)

[18] Wooley WD, Fardell PJ, Fire Safety Journal., 5, 29 (1982)

[19] Baek HD, Seo SH, Korea Patent 1020100052656 (2010)

[20] Kang YM, Song BM, Lee JS, Kim HS, Seo SH, Arch Virol, DOI 10.1007/s00705-010-0914-7 (2011)

[21] Russel AD, Hugo WB, Ayliffe GAJ, Principles and Practice of Disinfection, Preservation and Sterilization, 3rd ed., Oxford, Blackwell Science Ltd., pp124-148 (1999)

[22] Arias-Moliz MT, Ferrer-Luque CM, Espigares-Rodriguez E, Liebana-Urena J, Espigares-Garcia M, OOOOE (Oral Surg Oral Med Oral Pathol Oral Radiol Endod)., 106, 84 (2008)

[23] Lee SM, Lee BS, T. Byun TG, Song, KC, Colloid Surface A., 355, 167 (2010)

[24] Tan SZ, Ding LC, Liu YL, Ouyang YS, Chen YB, Chin. Chem. Lett., 18, 85 (2007)

[25] Bryaskova R, Pencheva D, Kale GM, Lad U, Kantardjiev T, J. Colloid Interface Sci., 349(1), 77 (2010)

[26] Hwang TS, Lee BJ, Yang YK, Choi JH, Kim HJ, Prospect. Ind. Chem., 8(6), 36 (2005)