Inorganic Chemistry, Vol.35, No.25, 7443-7444, 1996
Molecular-Structure of (Cpfe(Co)(2))2Alar (Ar=2-((Dimethylamino)Methyl)Phenyl) - An Alanediyl Complex with 2 Fe-Al Bonds
Two new Fe-Al complexes ArAl[CpFe(CO)(2)]Cl (1) and ArAl[CpFe(CO)(2)](2) (2) (Ar = 2-[(dimethylamino)methyl]phenyl), respectively, were synthesized by the reaction of ArAlCl2 with 1 or 2 equiv of Na[CpFe(CO)(2)]. The structures of these products were deduced from NMR (H-1, C-13, Al-27) and IR measurements and are confirmed by X-ray structural determination of 2.
Keywords:HYDRIDES