Electronic properties of MoO2 bulk and (0 1 1) surface are discussed. It is found that Fermi level is located within the band dominated by d molybdenum orbitals, thereby reflecting the metallic character of the system. Results for (0 1 1)MoO2 surface indicate that the surface retains the metallic character of the bulk Depending on the thickness of the slab used to model the surface (1-layer or 2-layers) the electronic structure and properties change. In the 2-layer slab, bands close to the Fermi level originate both from regular six-fold coordinated Mo(6) centers as well as from five-fold coordinated Mo(5) centers occurring due to surface formation. In the 1-layer slab, peaks right below the Fermi level are dominated by the surface centers that are six-fold coordinated Mo(6) but also centers which are effectively four-fold coordinated Mo(4). This has a profound effect on the reactivity as was tested by a probe reaction of H-2 adsorption, which did not interact with the surface described by the 2-layer slab, but underwent dissociation on the 1-layer slab. The Mo-Mo pairs with bonds of approximately single character, characteristic for the bulk structure, are also present on the surface, both on 1-layer and 2-layer slabs. The local properties of (0 1 1)MoO2 surface are very similar to other transition metal oxides. Metal-oxygen bonds are of a mixed ionic and covalent nature and the nucleophilicity of oxygen increases with the increase of coordination numbers of the corresponding oxygen atoms. (C) 2010 Elsevier B.V. All rights reserved.