Platinum plays an important, multi-functional role during NOx storage and reduction (NSR). Understanding and predicting the effect of Pt loading is essential to optimize the lean NOx trap. In this study, a microkinetic model is developed for NOx storage on a series of Pt/BaO/Al2O3 catalysts with a range of Pt loadings (0-3.7 wt.%). A classification of the Ba sites into two storage site populations, proximal and non-proximal (bulk), is presented. A simple model for estimating the capacities of the two Ba site populations using the Pt loading is used to explain trends in the storage of NO/O-2 and NO2/O-2. The model integrates existing literature models for NO2 storage on BaO/Al2O3, Pt-catalyzed NO oxidation to NO2, and spillover chemistry involving NO2. Wherever possible, simplifications in the model are made based on sensitivity analyses. Literature estimates of kinetic parameters are adjusted if estimates of spillover rate constants are not sufficient to predict the storage data. The dual-site model comprises proximal storage sites that participate in the spillover chemistry and non-proximal sites that involve NO2 that is generated by the Pt-catalyzed NO oxidation. The model shows reasonable agreement with the measured storage of NO and NO2 in O-2 at 340 degrees C for a range of storage times and Pt loading. The model helps to elucidate the storage dynamics and the roles of Pt and should be useful for incorporation into a complete NOx storage and reduction model. Some further refinements to the model are discussed. (C) 2011 Elsevier B.V. All rights reserved.