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Chemical Engineering Journal, Vol.166, No.1, 454-459, 2011
Adsorption of copper on amine-functionalized SBA-15 prepared by co-condensation: Kinetics properties
Amino-functionalized SBA-15 prepared by co-condensation was tested for the removal of copper ions from aqueous solutions under different temperatures, pH, initial concentrations and agitation speeds. The obtained results indicated that the amino-functionalized SBA-15 was very efficient and equilibrium was achieved in less than 30 min at room temperature. The kinetic data was analyzed using four models, namely the first-order, the pseudo first- and second-order and the intraparticle diffusion model. Within the conditions used, the pseudo second-order kinetic model provided the best fit to the experimental data. Applying the intraparticle model showed that the adsorption involved three different stages. (C) 2010 Elsevier B.V. All rights reserved.
Keywords:Heavy metals removal;Mesoporous silica;Amine-functionalized SBA-15;Adsorption;Co-condensation;Kinetics