Inorganic Chemistry, Vol.37, No.13, 3415-3418, 1998
Novel organically templated vanadyl(IV) diarsenate and monoarsenate with chain structures: Solvothermal synthesis and characterization of (H3NC2H4NH3)[VO(H2O)As2O7] and (H3NC2H4NH3)(0.5)[VO(H2O)AsO4]
The synthesis and characterization of two 1D chain vanadyl(IV) arsenates are described; one infinite chain is built up of VO5(H2O) octahedra and As2O7 bitetrahedra, and the other is formed of edge-sharing [V2O8-(H2O)(2)] bioctahedra and AsO4 tetrahedra.