The reactivity of titanium-vanadium containing groups in the synthesis of two-component monolayers on silica surfaces

A.A. Malygin; D.D. Stanislaw; Chul-Tae Lee

Journal of Industrial and Engineering Chemistry, Vol.18, No.1, 456-461, January, 2012

DOI10.1016/j.jiec.2011.11.024 Export Citation

The reactivity of titanium-vanadium containing groups in the synthesis of two-component monolayers on silica surfaces

A.A. Malygin, D.D. Stanislaw, and Chul-Tae Lee^{1, †}

Department of Chemical Technology of Materials and Devices of Electronic Industry, St. Petersburg State Institute of Technology, St. Petersburg 198013, Russia, Russian Federation
¹Department of Chemical Engineering, Dankook University, Gyeonggi-do 448-701, Republic of Korea

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The coating of silica surfaces with two-component VOCl3 and TiCl4 monolayers was studied with respect to the composition of the products and the kinetics of interaction. The titanium and vanadiumcontaining groups were found to be able to replace each other equivalently. Surface sites were found to determine reactivity, as were lateral interactions in the monolayer. The results found the presence of two kinds of active center; with the estimated ratio of such groups correlating with data from chemical analyses of the concentrations of groups covalently linked to the surface by different numbers of bonds.

Keywords:Silica surface;Monolayer;Titanium;Vanadium;Modification

[References]

Malygin AA, J. Ind. Eng. Chem., 12(1), 1 (2006)
Lisichkin GV, Fadeev AY, Serdan AA, Nesterenko PN, Mingalyov PG, Furman DB, Chemistry of Surface Grafted Compounds, Lisichkin, Moscow (in Russian). (2003)
Mikko R, Appl. Surf. Sci., 112, 223 (1997)
Malygin AA, Malkov AA, Dubrovenskii SD, Studies in Surface Science and Catalysis, Elsevier, Amsterdam, 213 (1996)
Malygin AA, Smirnov VM, Solid State Technol., 14 (2002)
Suntola T, Mater. Sci. Rep., 4(7), 261 (1989)
Drosd VE, Tolstoy VP, Appl. Surf. Sci., 112, 269 (1997)
Leskela M, Ritala M, Thin Solid Films, 409(1), 138 (2002)
Gun'ko VM, Leboda R, Marciniak M, Grzegorczyk W, Skubiszewska-Zieba J, Malygin AA, Malkov AA, Langmuir, 16(7), 3227 (2000)
Leboda R, Marciniak M, Gun’ko VM, Grzegorczyk W, Malkov AA, Malygin AA, J. Colloid Interface Sci., 167, 275 (2000)
Malygin AA, Ermilova MM, Gryaznov VM, Orekhova NV, International Congress on Membranes and Membrane Processes (ICOM), Toulouse, France, July 7-12, 433 (2002)
Gusarov VV, Ishutina ZN, Malkov AA, Malygin AA, Inorg. Mater., 36(11), 1342 (2000)
Malygin AA, J. Appl. Chem., 49(8), 1686 (1979)
Malygin AA, Kol’tsov SI, Napravlennii sintez tverdykh veshchestv, vol. 1, Leningrad State University, Leningrad, (in Russian)., 17 (1983)
Evdokimov AV, Malygin AA, Kol’tsov SI, J. Appl. Chem., (Russian Ed.)., 57(4), 749 (1987)
Malygin AA, Volkova AN, Koltzov SI, Aleskovskii VB, J. Common Chem., (Russian Ed.)., 43(7), 1436 (1973)
Bulatov MI, Kalinkin IP, A Practical Manual on Photocolourimetric and Spectrophotometric Methods of the Analysis, Khimia, Leningrad, (in Russian). (1976)
Sharlo G, Methods of Analytical Chemistry, Khimia, Moscow, (in Russian). (1969)
Vasil’ev FP, Numerical Methods of the Solving of Extreme Tasks, Nauka, Moscow, (in Russian). (1988)
Dubrovensky SD, Malygin AA, J. Appl. Chem., (Russian Ed.)., 64(2), 177 (1994)
Malkov AA, Sosnov EA, Osipenkova OV, Malygin AA, Appl. Surf. Sci., 108(1), 133 (1997)
Tovbin JK, The Theory of Physical.Chemical Processes at the Gas.Solid Interface, Mir, Moscow, (in Russian). (1991)

[Related Articles]

[1] Malygin AA, J. Ind. Eng. Chem., 12(1), 1 (2006)

[2] Lisichkin GV, Fadeev AY, Serdan AA, Nesterenko PN, Mingalyov PG, Furman DB, Chemistry of Surface Grafted Compounds, Lisichkin, Moscow (in Russian). (2003)

[3] Mikko R, Appl. Surf. Sci., 112, 223 (1997)

[4] Malygin AA, Malkov AA, Dubrovenskii SD, Studies in Surface Science and Catalysis, Elsevier, Amsterdam, 213 (1996)

[5] Malygin AA, Smirnov VM, Solid State Technol., 14 (2002)

[6] Suntola T, Mater. Sci. Rep., 4(7), 261 (1989)

[7] Drosd VE, Tolstoy VP, Appl. Surf. Sci., 112, 269 (1997)

[8] Leskela M, Ritala M, Thin Solid Films, 409(1), 138 (2002)

[9] Gun'ko VM, Leboda R, Marciniak M, Grzegorczyk W, Skubiszewska-Zieba J, Malygin AA, Malkov AA, Langmuir, 16(7), 3227 (2000)

[10] Leboda R, Marciniak M, Gun’ko VM, Grzegorczyk W, Malkov AA, Malygin AA, J. Colloid Interface Sci., 167, 275 (2000)

[11] Malygin AA, Ermilova MM, Gryaznov VM, Orekhova NV, International Congress on Membranes and Membrane Processes (ICOM), Toulouse, France, July 7-12, 433 (2002)

[12] Gusarov VV, Ishutina ZN, Malkov AA, Malygin AA, Inorg. Mater., 36(11), 1342 (2000)

[13] Malygin AA, J. Appl. Chem., 49(8), 1686 (1979)

[14] Malygin AA, Kol’tsov SI, Napravlennii sintez tverdykh veshchestv, vol. 1, Leningrad State University, Leningrad, (in Russian)., 17 (1983)

[15] Evdokimov AV, Malygin AA, Kol’tsov SI, J. Appl. Chem., (Russian Ed.)., 57(4), 749 (1987)

[16] Malygin AA, Volkova AN, Koltzov SI, Aleskovskii VB, J. Common Chem., (Russian Ed.)., 43(7), 1436 (1973)

[17] Bulatov MI, Kalinkin IP, A Practical Manual on Photocolourimetric and Spectrophotometric Methods of the Analysis, Khimia, Leningrad, (in Russian). (1976)

[18] Sharlo G, Methods of Analytical Chemistry, Khimia, Moscow, (in Russian). (1969)

[19] Vasil’ev FP, Numerical Methods of the Solving of Extreme Tasks, Nauka, Moscow, (in Russian). (1988)

[20] Dubrovensky SD, Malygin AA, J. Appl. Chem., (Russian Ed.)., 64(2), 177 (1994)

[21] Malkov AA, Sosnov EA, Osipenkova OV, Malygin AA, Appl. Surf. Sci., 108(1), 133 (1997)

[22] Tovbin JK, The Theory of Physical.Chemical Processes at the Gas.Solid Interface, Mir, Moscow, (in Russian). (1991)