A study of species formation of aqueous tertiary and hindered amines using quantitative 13C NMR spectroscopy

Jeong Ho Choi; Seong Geun Oh; Yeo Il Yoon; Soon kwan Jeong; Kyung Ryong Jang; Sung Chan Nam

Journal of Industrial and Engineering Chemistry, Vol.18, No.1, 568-573, January, 2012

DOI10.1016/j.jiec.2011.11.053 Export Citation

A study of species formation of aqueous tertiary and hindered amines using quantitative 13C NMR spectroscopy

Jeong Ho Choi^{1, 2}, Seong Geun Oh², Yeo Il Yoon¹, Soon kwan Jeong¹, Kyung Ryong Jang³, and Sung Chan Nam^{1, †}

¹Korea Institute of Energy Research, Daejeon 305-343, Republic of Korea
²Hanyang University, Seoul 133-791, Republic of Korea
³Korea Electric Power Research Institute, Daejeon 305-380, Republic of Korea

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Tertiary and sterically hindered amines have been chosen as potential candidate absorbents, recommended for their high carbon dioxide (CO2) loading capacity and easy regeneration. In this study, the CO2 absorption characteristics of these amines were studied using 1H nuclear magnetic resonance (NMR) and quantitative 13C NMR. The equilibrium experiments were conducted in the vapor. liquid equilibrium (VLE) apparatus, which was used to measure the CO2 absorption capacities and relative absorption rates of aqueous solutions of methyldiethanolamine (MDEA), 2-amino-2-methyl-1-propanol (AMP). The CO2 loaded absorbents were used for NMR measurement to determine the distribution of species formed in the absorbents. This process confirmed the reaction mechanisms of the individual absorbents in relation to CO2 absorption capacities.

Keywords:Carbon dioxide;Hindered amine;Tertiary amine

[References]

Satori G, Savage DW, Ind. Eng. Chem. Fundam., 22, 239 (1983)
Samanta A, Bandyopadhyay SS, Chem. Eng. Sci., 64(6), 1185 (2009)
Amann JMG, Bouallou C, Eng. Proc., 1, 901 (2009)
Mandala BP, Biswas AK, Bandyopadhyay SS, Chem. Eng. Sci., 58(18), 4137 (2003)
Glasscock DA, Critchfield JE, Rochelle GT, Chem. Eng. Sci., 46, 2829 (1991)
Versteeg GF, Van Swaaij WPM, Ind. Eng. Chem. Fundam., 19, 260 (1980)
Bosch H, Versteeg GF, Van Swaaij WPM, Chem. Eng. Sci., 45, 1167 (1990)
Xu S, Wang YW, Otto FD, Mather AE, Chem. Eng. Sci., 51(6), 841 (1996)
Sharma MM, Trans. Faraday Soc., 61, 681 (1965)
Alper E, Ind. Eng. Chem. Res., 29, 1725 (1990)
da Silva EF, Svendsen HF, Ind. Eng. Chem. Res., 43(13), 3413 (2004)
Donaldson TL, Nguyen YN, Ind. Eng. Chem. Fundam., 19, 260 (1980)
Singh P, Niederer JPM, Versteeg GF, Int. J. Greenhouse Gas Control., 1, 5 (2007)
Mandal BP, Bandyopadhyay SS, Chem. Eng. Sci., 61(16), 5440 (2006)
Yang Q, Bown M, Ali A, Winkler D, Puxty G, Attalla M, Eng. Proc., 1, 955 (2009)
Mani F, Peruzzini M, Stoppioni P, Green Chem., 8, 995 (2006)
Varzagli F, Mani F, Peruzzini M, Energy Environ. Sci., 2, 322 (2009)

[Referenced By]

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[1] Satori G, Savage DW, Ind. Eng. Chem. Fundam., 22, 239 (1983)

[2] Samanta A, Bandyopadhyay SS, Chem. Eng. Sci., 64(6), 1185 (2009)

[3] Amann JMG, Bouallou C, Eng. Proc., 1, 901 (2009)

[4] Mandala BP, Biswas AK, Bandyopadhyay SS, Chem. Eng. Sci., 58(18), 4137 (2003)

[5] Glasscock DA, Critchfield JE, Rochelle GT, Chem. Eng. Sci., 46, 2829 (1991)

[6] Versteeg GF, Van Swaaij WPM, Ind. Eng. Chem. Fundam., 19, 260 (1980)

[7] Bosch H, Versteeg GF, Van Swaaij WPM, Chem. Eng. Sci., 45, 1167 (1990)

[8] Xu S, Wang YW, Otto FD, Mather AE, Chem. Eng. Sci., 51(6), 841 (1996)

[9] Sharma MM, Trans. Faraday Soc., 61, 681 (1965)

[10] Alper E, Ind. Eng. Chem. Res., 29, 1725 (1990)

[11] da Silva EF, Svendsen HF, Ind. Eng. Chem. Res., 43(13), 3413 (2004)

[12] Donaldson TL, Nguyen YN, Ind. Eng. Chem. Fundam., 19, 260 (1980)

[13] Singh P, Niederer JPM, Versteeg GF, Int. J. Greenhouse Gas Control., 1, 5 (2007)

[14] Mandal BP, Bandyopadhyay SS, Chem. Eng. Sci., 61(16), 5440 (2006)

[15] Yang Q, Bown M, Ali A, Winkler D, Puxty G, Attalla M, Eng. Proc., 1, 955 (2009)

[16] Mani F, Peruzzini M, Stoppioni P, Green Chem., 8, 995 (2006)

[17] Varzagli F, Mani F, Peruzzini M, Energy Environ. Sci., 2, 322 (2009)