화학공학소재연구정보센터
Korean Journal of Chemical Engineering, Vol.29, No.5, 549-554, May, 2012
Removal of gaseous toluene by using TiO2 film doped of Ru-dye/Pt in a pilot scale photoreactor
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The photodegradation efficiency (PE) of gaseous toluene was investigated by using titanium dioxide (TiO2) film doped of ruthenium (Ru)-dye/platinum (Pt) in a 3,600 L pilot reactor. Ru-dye was applied as a sensitizer to enhance PE of toluene in both UV and visible wavelength range since its major peaks are 225 nm, 325 nm, 375 nm, and 525 nm. PE by using Pt/TiO2 was more enhanced since Pt plays a role as an electron trapper in UV light range. The 3.2 μm thickness of TiO2 film was optimized for the highest PE. The highest PE was 75%, 85%, and 90% by TiO2, Pt/TiO2, and Ru-dye/Pt/TiO2 film, respectively.
  1. Kang M, Kim BJ, Cho SM, Chung CH, Kim BW, Han GY, Yoon KJ, J. Mol. Catal. A-Chem., 180(1-2), 125 (2002)
  2. Jothiramalingam R, Wang MK, J. Hazard. Mater., 147(1-2), 562 (2007)
  3. Jeong J, Sekiguchi K, Sakamoto K, Chemosphere., 57, 663 (2004)
  4. Maira AJ, Yeung KL, Soria J, Coronado JM, Belver C, Lee CY, Appl. Catal. B: Environ., 29(4), 327 (2001)
  5. Pengyi Z, Fuyan L, Gang Y, Qing C, Wanpeng Z, J. Photochem. A: Chem., 156, 189 (2003)
  6. Keller N, Barraud E, Bosc F, Edwards D, Keller V, Appl. Catal. B: Environ., 70(1-4), 423 (2007)
  7. Shen M, Wu Z, Huang H, Du Y, Zou Z, Yang P, Mater. Lett., 60, 693 (2006)
  8. Chatterjee D, Dasgupta S, J. Photochem. Photobio. C: Photochem. Rev., 6, 186 (2005)
  9. Wu SJ, Chen CY, Chen JG, Li JY, Tung YL, Ho KC, Wu CG, Dyes Pigm., 84, 95 (2010)
  10. Ozcan O, Yukruk F, Akkaya EU, Uner D, Appl. Catal. B: Environ., 71(3-4), 291 (2007)
  11. Zou JJ, Chen C, Liu CJ, Zhang YP, Han Y, Cui L, Mater.Lett., 59, 3437 (2005)
  12. Ishibai Y, Sato J, Nishikawa T, Miyagishi S, Appl. Catal. B: Environ., 79(2), 117 (2008)
  13. Sivakumar R, Marcelis ATM, Anandan S, J. Photochem. Photobiol. A: Chem., 208, 154 (2009)
  14. Chen X, Mao SS, Chem. Rev., 107(7), 2891 (2007)
  15. Yoon J, Bae S, Shim E, Joo H, Korean J. Chem. Eng., 24(6), 1031 (2007)
  16. Vergara-Fernandez A, Molina LL, Pulido NA, Aroca G, J.Environ. Manage., 84, 115 (2007)
  17. Jang SJ, Kim MS, Kim BW, J. Ind. Eng. Chem., 10(4), 544 (2004)
  18. Jang SJ, Kim MS, Kim BW, Water Res., 39, 2178 (2005)
  19. Lee JM, Kim MS, Kim BW, Water Res., 38, 3605 (2004)
  20. Ban JY, Son YH, Lee SC, Kang M, Choung SJ, Sung JY, J. Korean Ind. Eng. Chem., 16(3), 413 (2005)
  21. Jeong J, Sekiguchi K, Sakamoto K, Chemosphere., 57, 663 (2004)
  22. Kay A, Gratzel M, Sol. Energy Mater. Sol. C., 44, 99 (1996)
  23. Falconer JL, Magrini-Bair KA, J. Catal., 179(1), 171 (1998)
  24. d’Hennezel O, Pichat P, Oillis DF, J. Photochem. Photobiol.A: Chem., 118, 197 (1998)