화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Korean Journal of Chemical Engineering, Vol.17, No.4, 480-483, July, 2000
DOI10.1007/BF02706865  Export Citation
Shape-Selective Alkyoation of Isopropylnaphthalene on MCM-22 Zeolite
Myung-Wan Kim, Jong-Ho Kim, Yoshihiro Sugi1, and Gon Seo†
  • Department of Chemical Technology & The Research Institute for Catalysis, Chonnam National University, Kwangju 500-757, Korea
  • 1Department of Chemistry, Faculty of Engineering, Gifu University, Gifu 501-1193, Japan
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An MCM-22 zeolite with an Si/Al ratio 13 was found to exhibit higher selectivity to β,β-diisopropylnaphthalene in the alkylation of isopropylnaphthalene with isopropylalcohol, as compared with other zeolites such as mordenite, Y and beta having similar Si/Al ratios. This high selectivity is ascribed to the specific pore shape of MCM-22 zeolite. The gradual increase in the selectivity with reaction time is due to its pore modification by coke deposit.
Keywords:MCM-22 Zeolite;Shape-Selective Alkylation;Isopropylnaphthalene;β;β-Diisopropylnaphthalene;Specific Pore Shape
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