화학공학소재연구정보센터
Electrochemical and Solid State Letters, Vol.14, No.9, H380-H384, 2011
Correlation of Collapse Forces Determined by Lateral Force AFM with Damage Generation due to Physical Cleaning Processes
Four types of silicon FINs on SiO2 were used as test structures for damage analysis: amorphous Si (a-Si), annealed Si (a*-Si), as-deposited poly-Si (p-Si) and crystalline silicon (c-Si). The collapse of single FINs was analyzed by lateral force AFM measurement and the damage due to a physical cleaning process was optically evaluated in parallel. The number of damaged FINs and the collapse force were compared. We observed a clear correlation between the damage counts and structure strengths. For both mega-sonic and spray cleaning techniques the damage decreases in the order a-Si > poly-Si > a*-Si > c-Si. The collapse forces increase in the same order 0.5 mN (a-Si) < 0.8 mN (poly-Si) < 1.0 mN (a*-Si) < 1.6 mN (c-Si). This remarkable correlation can be explained by structure and interface strength. The collapse behavior of a-Si FINs is also different from poly-Si FINs. a-Si FINs delaminate, break at one end, bend and finally break at the other end creating long fragments, as observed by AFM. Poly-Si and a*-Si FINs break at two ends simultaneously and create smaller fragments. This mechanism was also confirmed by detailed classification of the defects generated by physical forces during a cleaning process using physical forces. (C) 2011 The Electrochemical Society. [DOI: 10.1149/1.3603854] All rights reserved.