Syntheses and characterizations of the novel dodecanuclear heterobimetallic cage clusters : [Et4N](2)[(M(2)Cu(2)S(2)O(2)edt(2))(3)(mu(6)-S-2)]center dot CH2Cl2 (M = Mo, W; edt = -SC2H4S-)

Lin P; Wu XT; Huang Q; Wang QM; Sheng TL; Zhang WJ; Guo J; Lu JX

Inorganic Chemistry, Vol.37, No.21, 5672-5674, 1998

Lin P, Wu XT, Huang Q, Wang QM, Sheng TL, Zhang WJ, Guo J, Lu JX

The anions of [Et4N](2)[(M(2)Cu(2)S(2)O(2)edt(2))(3)(mu(6)-S-2)] . CH2-Cl-2 (M = Mo, W) can be viewed as a cage with an S-2(2-) group at the center. Each S atom of S-2(2-) is bound to three Cu atoms.

Keywords:CUBANE-LIKE