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Inorganic Chemistry, Vol.38, No.2, 208-209, 1999
One-dimensional coordination polymers based upon bridging terephthalate ions
The reaction between transition metal halides MX2 (where M = Co(II) and Ni(II)) in an aqueous solution containing disodium terephthalate along with pyridine-based ligands gives rise to one-dimensional coordination polymers. Both [M(terephthalate)(4-picoline)(2)(H2O)(2)]. 2(4-picoline) (1) and [M(terephthalate)(pyridine)(2)(H2O)2]. 2(pyridine). 2(H2O) (2) have been isolated. These frameworks exhibit hydrogen bond donors running along the backbone of each polymer, which gives rise to inclusion chemistry between the framework and pyridine guest molecules.
Keywords:CRYSTAL-STRUCTURE;MAGNETIC-PROPERTIES;4;4'-BIPYRIDINE;COPPER(II);NICKEL(II);COMPLEXES;COMPOUND;ABILITY;CHAIN;TA