화학공학소재연구정보센터
Industrial & Engineering Chemistry Research, Vol.50, No.18, 10476-10479, 2011
Gas-Limited Hydrogenation of 1-Octene in a Fixed Bed: Upflow Versus Downflow
Two downflow operational modes with different hydrodynamic states were compared to upflow operation. Various gas-limited conditions (gamma = 15-60) were employed. The downflow mode with the higher wetting efficiency consistently outperformed the downflow mode with the lower wetting efficiency. Both downflow modes outperformed the upflow mode at high gas mass fluxes and underachieved against upflow at lower gas mass fluxes. The results stand in contradiction to the theory on direct gas-solid mass transfer under trickle-flow conditions. The switching behavior of the upflow mode performance was attributed to hydrodynamic regime shifts, hinting that the perceived "poor" performance of upflow reactors under gas limited conditions might be linked to slugging in laboratory-scale reactors.