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Inorganic Chemistry, Vol.49, No.3, 769-771, 2010
Unprecedented Marriage of a Cationic Pentanuclear Cluster and a 2D Polymeric Anionic Layer Based on a Flexible Tripodal Ligand and a Cu-II Ion
The anionic CdI2 center dot type topological net, [Cu-2(tci)(2)](2-), and the pentanuclear copper custer cation [Cu-5(tci)(2)(OH)(2)(H2O)(8)](2+) [tci = tris-(2-carboxyethyl)isocyanurate] form a complementary 3D supramolecular framework. Interestingly, there exist centrosymmetric cyclic (H2O)(18) clusters in the cavities.