Inorganic Chemistry, Vol.49, No.22, 10241-10243, 2010
Hard/Soft Heterometallic Network Complex of a Macrocycle with Endo/Exocyclic Coordination
One-pot assembly reactions of an S2O4 macrocycle with Cul in the absence and presence of KI afforded an emissive one-dimensional looped coordination polymer linked with a cubane-type copper iodide cluster and an endocoordinated potassium(I) coordination polymer linked with a ribbon-type copper iodide cluster, respectively.