Inorganic Chemistry, Vol.38, No.22, 5189-5191, 1999
1,2-cyclopentadienyl diimine-group 13 complexes
The complexes [(1,2-C5H3(C(Ph)NH)(2))]MR2, M = Al, R = Cl (1), Me (3), Et (4), CH2Ph (5), Ph (6), M = Ga, R = Cl (2), Me (7), Et (8), CH2Ph (9), Ph (10), are readily prepared. X-ray studies of 1-3 suggest a charge separation and thus electrophilic metal centers.