The heat transfer characteristics of supercritical pressure water in a vertically-upward optimized internally-ribbed tube was investigated experimentally to study the mechanisms of unusual heat transfer of supercritical pressure water in the so-called large specific heat region. The experimental parameters were as follows. The pressure at the inlet of the test section ranged from 22.5 to 29.0 MPa, and the mass flux of the fluid was from 650 to 1200 kg/m(2) s, and the heat flux on the inside wall of the tube varied from 200 to 660 kW/m(2). According to experimental data, the characteristics of heat transfer enhancement and also the heat transfer deterioration of supercritical pressure water in the large specific heat region was analyzed and based on the comparison and analysis of the current major theories that were used to explain the reasons for unusual heat transfer to occur, the mechanisms of heat transfer enhancement and deterioration were discussed, respectively. The enhanced heat transfer was characterized by the gently changing wall temperature, the small temperature difference between the inside-tube-wall and the bulk fluid and the high heat transfer coefficient in comparison to the normal heat transfer. The deteriorated heat transfer could be characterized by the sharply increasing wall temperature, the large temperature difference and a sudden decrease in heat transfer coefficient in comparison to the normal heat transfer. The heat transfer enhancement of the supercritical pressure water in the large specific heat region was suggested to be a result of combined effect caused by the rapid variations of thermophysical properties of the supercritical pressure water in the large specific heat region, and the same was true of the heat transfer deterioration. The drastic changes in thermophysical properties near the pseudocritical points, especially the sudden rise in the specific heat of water at supercritical pressures, might result in the occurrence of the heat transfer enhancement, while the covering of the heat transfer surface by fluids lighter and hotter than the bulk fluid made the heat transfer deteriorated eventually and explained how this lighter fluid layer formed. (C) 2011 Elsevier Ltd. All rights reserved.