International Journal of Heat and Mass Transfer, Vol.54, No.17-18, 4135-4142, 2011
Preliminary investigation of factors determining self-organised structures preparation in polymer layers
Factors determining creation of self-organized structures. Benar-Marangoni cells, during the process of solvent evaporation from the polymer solution and formation of polymer film were studied. Examined parameters were temperature, temperature gradient, rate of drying, height of a liquid layer, area for film preparation, viscosity, molecular weight distribution, etc. A special apparatus, micro condensation drying system, was engineered for this study. As a model system, hydroxyethyl cellulose aqueous solution was used for its excellent film-forming ability and the tendency to self-aggregation. Experimental results, presented in a wide spectrum of self-organized patterns, show the complexity of the problem and the crucial role of molecular weight distribution of the polymer in the fixation of organized structures under highly non-equilibrium conditions. (C) 2011 Elsevier Ltd. All rights reserved.
Keywords:Self-organization;Convection;Evaporation;Process parameters;Polymer solution;Hydroxyethyl cellulose;Molecular weights