Inorganic Chemistry, Vol.39, No.4, 632-633, 2000
Reactivity of the iron porphyrin Fe(TPP)(NO) with excess NO. Formation of Fe(TPP)(NO)(NO2) occurs via reaction with trace NO2
Fe(TPP)(NO) (TPP = tetraphenylporphyrinato dianion) does not react observably with excess NO in organic solvents at ambient pressure and temperature; however, adventitious NO2 rapidly leads to the nitrosyl nitro product Fe(TPP)(NO)(NO2), which is labile toward loss of Nd. [GRAPHICS]
Keywords:NITRIC-OXIDE;IRON(III) PORPHYRIN;STRUCTURAL CHARACTERIZATION;MOLECULAR STEREOCHEMISTRY;COMPLEXES;PHOTOLYSIS