Poly(vinyl alcohol) (PVA) was chosen as a controllable gelator to prepare sodium alginate (SA)-based physically cross-linked dual-responsive hydrogel by three steps. First, polyvinyl acetate (PVAc) was grafted onto SA via radical copolymerization. Then, the copolymer was subsequently converted into SA-g-poly(vinyl alcohol) (SAPVA) by alcoholysis reaction. PVA content of SAPVA was tailored by controlling the graft percentage of PVAc, i.e. through varying the amount of vinyl acetate during copolymerization. Finally, SAPVA hydrogels were formed by freezing-thawing cycles. The structure of the graft copolymers was verified with FTIR spectroscopy. X-ray diffraction analysis results revealed that the crystallinity of SAPVA hydrogels depended on the PVA content of SAPVA. The swelling test showed that SAPVA hydrogels were pH-responsive, and the swelling was reversible. SAPVA hydrogels also behaved electric-responsive. In addition, the pH-sensitivity of SAPVA hydrogels was able to be controlled with the composition of the hydrogels. (C) 2011 Wiley Periodicals, Inc. J Appl Polym Sci 123: 2244-2249, 2012