화학공학소재연구정보센터
Journal of Hazardous Materials, Vol.190, No.1-3, 285-292, 2011
Distillation of granulated scrap tires in a pilot plant
This paper reports the pyrolytic treatment of granulated scrap tires (GST) in a pilot distillation unit at moderate temperature (550 degrees C) and atmospheric pressure, to produce oil, char and gas products. Tire-derived oil is a complex mixture of organic C(5)-C(24) compounds, including a very large proportion of aromatic compounds. This oil has a high gross calorific value (similar to 43 MJ kg(-1)) and N and S contents of 0.4% and 0.6%, respectively, falling within the specifications of certain heating fuels. The distillation gas is composed of hydrocarbons; methane and n-butane are the most abundant, investing the distillation gas with a very high gross calorific value (similar to 68 MJ N m(-3)). This gas is transformed into electric power by a cogeneration turbine. The distillation char is mostly made of carbon but with significant inorganic impurities (similar to 12 wt%). The quality of the solid residue of the process is comparable to that of some commercial chars. The quantity of residual solids, and the qualities of the gas, liquid and solid fractions, are similar to those obtained by conventional pyrolytic treatments of waste tires. However, the simplicity of the proposed technology and its low investment costs make it a very attractive alternative. (C) 2011 Elsevier B.V. All rights reserved.