Nanostructured carbon materials have attracted enormous attention in last two decades due to their unique chemical, electrical, and mechanical properties. In this work, amorphous hollow carbon spheres (AHCSs) with diameters in the range of 100-750 nm, which are dispersed among bent graphitized carbon nanotubes, are synthesized by using radio frequency plasma enhanced chemical vapor deposition in mixed CH(4)/H(2) gases. The carbon spheres were characterized with scanning electron microscope, energy-dispersive X-ray spectroscopy, Raman spectroscopy, and transmission electron microscopy. It is found that MgO and Co/Ni nanoparticles as well as hydrogen play crucial roles in the formation of AHCSs. Moreover, a possible growth mechanism of AHCSs was proposed. The results of this study provide new insights into the fundamental understanding of nonstructural carbon materials toward applications in nanodevices.