Precombustion CO(2) capture is an important option for the management of greenhouse gas emissions from power generation, because the higher concentrations can lead to improved separation economics. Membranes can provide a significant boost in the performance by separating CO(2) at high temperature and at high pressure, provided they are properly integrated into a power plant. In this study, membrane performance targets were derived for CO(2) capture using H(2)-selective membranes in integrated gasification combined cycle (IGCC) power plant systems. Three key differences were found relative to plants configured for the production of industrial-grade H(2). First, the H(2)/CO(2) selectivity requirement is lower when the permeate is combusted in a gas turbine, as opposed to purified for industrial use. Second, the membrane is subject to additional selectivity requirements. For example, CO(2) product purity specs impose a H(2)/N(2) selectivity requirement. Third, the plant design must account for the energy associated with unshifted CO, CH(4) and other fuel components that are not separated by the membrane. In contrast to H(2) production systems where the high H(2)/CO(2) selectivity requirement favors ultra-high selectivity metal-based membranes, the requirements for IGCC indicate a wider range of materials, including ceramic, zeolite. and polymeric membranes, should be considered. (C) 2010 Elsevier B.V. All rights reserved.