Electrochemical characterization and transport properties of polyvinyl chloride based carboxymethyl cellulose Ce(IV) molybdophosphate composite cation exchange membrane

Mohammad Mujahid Ali Khan; Rafiuddin; Inamuddin

Journal of Industrial and Engineering Chemistry, Vol.18, No.4, 1391-1397, July, 2012

DOI10.1016/j.jiec.2012.01.042 Export Citation

Electrochemical characterization and transport properties of polyvinyl chloride based carboxymethyl cellulose Ce(IV) molybdophosphate composite cation exchange membrane

Mohammad Mujahid Ali Khan, Rafiuddin^†, and Inamuddin¹

Membrane Research Laboratory, Department of Chemistry, Aligarh Muslim University, Aligarh 202002, India
¹Department of Applied Chemistry, Faculty of Engineering and Technology, Aligarh Muslim University, Aligarh 202002, India

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The polyvinyl chloride (PVC) based carboxymethyl cellulose Ce(IV) molybdophosphate composite membrane are prepared and characterized by the Scanning Electron Microscopy (SEM), X-ray diffraction (XRD), Fourier transformed infrared (FTIR), and thermogravimetric analysis (TGA) studies. The inorganic.organic composite membrane was found to be crystalline in nature with consistent arrangement of particles and indicating no sign of visible cracks. The FTIR spectra verify the binding of organic polymer with inorganic component. The membrane was found to be cation-selective. The order of surface charge density for uni-univalent electrolytes solution was found to be KCl > NaCl > LiCl.

Keywords:Composite membrane;Membrane potential;Fixed charge density;Mobility ratio;Distribution coefficient;Transport number

[References]

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Bullen RA, Arnot TC, Lakeman JB, Walsh FC, Biosens. Bioelectron., 21, 2015 (2006)
Nagarale RK, Gohil GS, Shahi VK, Trivedi GS, Rangarajan R, J. Colloid Interface Sci., 277(1), 162 (2004)
Baker RW, Membrane Technology and Applications, 2nd ed., Wiley, Chichester (2004)
Hussain AA, Nataraj SK, Abashar MEE, Al-Mutazb IS, Aminabhavi TM, J. Membr. Sci., 310(1-2), 321 (2008)
Khan MMA, Rafiuddin, Desalination, 272(1-3), 306 (2011)
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Teorell T, Proc. Natl. Acad. Sci. U.S.A., 21, 152 (1935)
Meyer KH, Sievers JF, Helv. Chim. Acta., 649, 665, and 987, 19 (1936)
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Khan AA, Khan A, Talanta., 72, 699 (2007)
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Ibrahim AA, Adel AM, El-Wahab ZHA, Al-Shemy MT, Carbohydr. Polym., 83, 94 (2011)
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Liang S, Teng F, Bulgan G, Zong R, Zhu Y, J. Phys. Chem. C., 112, 5307 (2008)
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Khan AA, Alam MM, Inamuddin, Mater. Res. Bull., 40, 289 (2005)
Khan AA, Alam MM, React. Funct. Polym., 55, 277 (2003)
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Barragan VM, Rueda C, Ruiz-Baura C, J. Colloid Interface Sci., 361, 172 (1995)
Lakshminarayanaiah N, Transport Phenomena in Membranes, Academic Press, New York (1969)
Shahi VK, Trivedi GS, Thampy SK, Rangarajan R, J. Colloid Interface Sci., 262(2), 566 (2003)
Choi JH, Moon SH, J. Membr. Sci., 191(1-2), 225 (2001)
Schaep J, Vandecasteele C, J. Membr. Sci., 188(1), 129 (2001)
Matsumoto H, Tanioka A, Murata T, Higa M, Horiuchi K, J. Phys. Chem. B, 102(25), 5011 (1998)
Chou TJ, Tanioka A, J. Colloid Interface Sci., 212(2), 293 (1999)

[Referenced By]

[1] Adhikari B, Majumdar S, Prog. Polym. Sci., 29, 699 (2004)

[2] Bullen RA, Arnot TC, Lakeman JB, Walsh FC, Biosens. Bioelectron., 21, 2015 (2006)

[3] Nagarale RK, Gohil GS, Shahi VK, Trivedi GS, Rangarajan R, J. Colloid Interface Sci., 277(1), 162 (2004)

[4] Baker RW, Membrane Technology and Applications, 2nd ed., Wiley, Chichester (2004)

[5] Hussain AA, Nataraj SK, Abashar MEE, Al-Mutazb IS, Aminabhavi TM, J. Membr. Sci., 310(1-2), 321 (2008)

[6] Khan MMA, Rafiuddin, Desalination, 272(1-3), 306 (2011)

[7] Teorell T, Proc. Soc. Exp. Biol., 33, 282 (1935)

[8] Teorell T, Proc. Natl. Acad. Sci. U.S.A., 21, 152 (1935)

[9] Meyer KH, Sievers JF, Helv. Chim. Acta., 649, 665, and 987, 19 (1936)

[10] Chou TJ, Tanioka A, J. Phys. Chem. B, 102(37), 7198 (1998)

[11] Singh K, Shahi VK, J. Membr. Sci., 49, 223 (1990)

[12] Mohammad A, Inamuddin, Amin A, Naushad M, Eldesoky GE, J.Therm. Anal. Calorim., (Revised), doi:10.1007/S 10973-011-2169-2. (2012)

[13] Coetzee CJ, Benson AJ, Anal. Chim. Acta., 57, 478 (1971)

[14] Craggs A, Moody GJ, Thomas JDR, J. Chem. Edu., 51, 541 (1974)

[15] Khan AA, Khan A, Talanta., 72, 699 (2007)

[16] Arfin T, Rafiuddin, J. Electroanal. Chem., 636, 113 (2009)

[17] ASTM D543-95, Standard Particles for Evaluating the Resistance of Plastics to Chemical Reagents, 27 (1998)

[18] Koter S, Piotrowski P, Kerres J, J. Membr. Sci., 153(1), 83 (1999)

[19] Titiloye JO, Hussain I, J. Colloid Interface Sci., 318, 50 (2008)

[20] Resina M, Macanas J, de Gyves J, Munˇ oz M, J. Membr. Sci., 289, 150158 (2007)

[21] Hebeish A, Higazy A, El-Shafei A, Sharaf S, Carbohydr. Polym., 79, 60 (2010)

[22] Ibrahim AA, Adel AM, El-Wahab ZHA, Al-Shemy MT, Carbohydr. Polym., 83, 94 (2011)

[23] Rao CNR, Chemical Applications of Infrared Spectroscopy, Academic Press, New York, 338 (1963)

[24] Liang S, Teng F, Bulgan G, Zong R, Zhu Y, J. Phys. Chem. C., 112, 5307 (2008)

[25] Duval D, Inorganic Thermogravimetric Analysis, Elsevier, Amsterdam (1963)

[26] Khan AA, Alam MM, Inamuddin, Mater. Res. Bull., 40, 289 (2005)

[27] Khan AA, Alam MM, React. Funct. Polym., 55, 277 (2003)

[28] Eisenman G, in: Kleinser A, Koty A (Eds.), Membrane Transport and Metabolism, Academic Press, New York, 163 (1961)

[29] Barragan VM, Rueda C, Ruiz-Baura C, J. Colloid Interface Sci., 361, 172 (1995)

[30] Lakshminarayanaiah N, Transport Phenomena in Membranes, Academic Press, New York (1969)

[31] Shahi VK, Trivedi GS, Thampy SK, Rangarajan R, J. Colloid Interface Sci., 262(2), 566 (2003)

[32] Choi JH, Moon SH, J. Membr. Sci., 191(1-2), 225 (2001)

[33] Schaep J, Vandecasteele C, J. Membr. Sci., 188(1), 129 (2001)

[34] Matsumoto H, Tanioka A, Murata T, Higa M, Horiuchi K, J. Phys. Chem. B, 102(25), 5011 (1998)

[35] Chou TJ, Tanioka A, J. Colloid Interface Sci., 212(2), 293 (1999)