화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.18, No.4, 1474-1481, July, 2012
DOI10.1016/j.jiec.2012.02.011  Export Citation
Microwave assisted solvent free synthesis of a,a9 -bis (arylidene) cycloalkanones by sulfated zirconia catalyzed cross aldol condensation of aromatic aldehydes and cycloalkanones
Kirat Rawal, Manish Kumar Mishra†, Manish Dixit, and Meka Srinivasarao
  • Department of Chemical Engineering and Shah-Schulman Center for Surface Science and Nanotechnology, Faculty of Technology, Dharmsinh Desai University, College Road, Nadiad – 387 001, Gujarat, India
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The catalytic application of sulfated zirconia as solid Brønsted acid catalyst was explored for cross aldol condensation reactions (Claisen Schmidt reaction). The synthesized catalyst was highly active for solvent free synthesis of α,α9 -bis(arylidene)cycloalkanones by cross aldol condensation of aromatic aldehydes with cycloalkanones. The microwave assisted synthesis resulted increased yields of the products (79-99%) at significantly lower reaction temperature (120-140 ℃) and reaction time (20 min) as compared to the synthesis by thermal heating (63-96% yield at 170 ℃ after 4 h). The microwave irradiation afforded selectively cross aldol products. The catalyst could be easily regenerated and reused several times with similar efficiency.
Keywords:Acid catalysis;Brønsted acidity;Cross aldol condensation;Claisen Schmidt reaction;Microwave irradiation;Sulfated zirconia
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