Journal of Physical Chemistry B, Vol.114, No.8, 2852-2855, 2010
Simple Geometrical Interpretation of the Linear Character for the Zeno-Line and the Rectilinear Diameter
The unified geometrical interpretation of the linear character of the Zeno-line (unit compressibility line Z = 1) and the rectilinear diameter is proposed. We show that recent findings about the properties of the Zeno-line and striking correlation with the rectilinear diameter line as well as other empirical relations can be naturally considered as the consequences of the projective isomorphism between the real molecular fluids and the lattice gas (Ising) model.