화학공학소재연구정보센터
Journal of the American Chemical Society, Vol.133, No.49, 19590-19593, 2011
Uniaxial Strain Orientation Dependence of Superconducting Transition Temperature (T-c) and Critical Superconducting Pressure (P-c) in beta-(BDA-TTP)(2)I-3
Dependence of the superconducting transition temperature (T-c) and critial superconducting pressure (Pc) of the pressure-induced superconductor beta-(BDA-TTP)(2)I-3 [BDA-TTP = 2,5-bis(1,3-dithian-2-ylidene)-1,3,4,6-tetrathiapentalene] on the orientation of uniaidal strain has been investigated. On the basis of the overlap between the upper and lower bands in the energy dispersion curve, the pressure orientation is thought to change the half-filled band to the quarter-filled one. The observed variations in Tc and Pc are explained by considering the degree of application of the pressure and the degree of contribution of the effective electronic correlation at uniaxial strains with different orientations parallel to the conducting donor layer.