Journal of the American Chemical Society, Vol.134, No.21, 8770-8773, 2012
Construction of 1,5-Enynes by Stereospecific Pd-Catalyzed Allyl-Propargyi Cross-Couplings
The palladium-catalyzed cross-coupling of chiral propargyl acetates and allyl boronates delivers chiral 1,5-enynes with excellent levels of chirality transfer and can be applied across a broad range of substrates.