A new approach to investigate upon the electrochemical properties of Super P carbon black anode material is attempted and compared with conventional mesophase pitch-based carbon fibers (MPCFs) anode material for lithium-ion batteries. The prepared Super P carbon black electrodes are characterized using transmission electron microscope (TEM). The assembled 2032-type coin cells are electrochemically characterized by ac impedance spectroscopic and cyclic voltammetric methods. The electrochemical performance of charge and discharge was analyzed using a battery cycler at 0.1 C rate and cut-off potentials of 1.20 and 0.01 V vs. Li/Li(+). The electrochemical test illustrates that the discharge capacity corresponding to Li intercalation into the Super P carbon black electrode is higher and coulombic efficiency is maintained approximately 84% at the end of the 20th cycling at room temperature. (C) 2011 Elsevier B.V. All rights reserved.