Microsingle crystals of poly(para-phenylene terephthalamide), abbreviated PPTA, were obtained by water-vapor induced precipitation of PPTA rigid-flexible copolymers in sulfuric acid solution. Electron diffraction was performed and yielded hk0 patterns. The crystal structure of a model compound, N, N' para (4-methoxycarbonyl) phenylene dibenzamide, abbreviated 3ARB-COOMe, is also reported. Its structure is compatible with that of the polymer, in which aromatic rings are all coplanar and form a 30 degrees angle with amide groups. A reinvestigation of form 11, based on electron diffraction data and molecular modeling simulations, is reported. The proposed space group is P112, and corresponds to a parallel chain arrangement, with terephthaloyl groups facing one another, and carbonyl groups pointing in opposite directions along the b-axis in adjacent hydrogen-bonded sheets. Chain conformation is the same as in form 1, as previously established. The 3ARB-COOMe conformation is suggested as a possible polymorph or as defects in the crystal phase. (C) 2011 Elsevier Ltd. All rights reserved.