Novel visible light-induced g-C3N4/Bi2WO6 composite photocatalysts were synthesized by introducing polymeric g-C3N4. The obtained g-C3N4/Bi2WO6 products were characterized by X-ray diffraction, scanning electron microscopy, transmission electron microscopy, high-resolution transmission electron microscopy, ultraviolet-visible diffuse reflection spectroscopy (DRS), and photoluminescence spectroscopy. The DRS results revealed that the g-C3N4/Bi2WO6 samples had a red shift and strong absorption in the visible light region. The photocatalytic oxidation ability of the novel photocatalyst was evaluated using methyl orange as a target pollutant. The photocatalysts exhibited a significantly enhanced photocatalytic performance in degrading methyl orange. The optimal g-C3N4 content for the photocatalytic activity of the heterojunction structures was determined. The synergic effect between g-C3N4 and Bi2WO6 was found to lead to an improved photo-generated carrier separation. Consequently, the photocatalytic performance of the g-C3N4/Bi2WO6 composites under visible light irradiation (lambda > 420 nm) was enhanced. The possible photocatalytic mechanism of the composites was proposed to guide the further improvement of their photocatalytic activity. (C) 2011 Elsevier B.V. All rights reserved.