Titania nanotubes are synthesized via hydrothermal treatment of TiO(2) powders in NaOH solution at 110 degrees C for 90 h, followed by annealing at 400 degrees C. The morphology of nanotubes is characterized by field-emission scanning electron microscopy (FESEM) and transmission electron microscopy (TEM). Microscopic observations on the transformation process indicate that the nanotubes retain their shapes after the annealing process. The crystalline structure and composition are examined by X-ray diffraction (XRD) and energy-dispersive X-ray spectroscopy (EDX). The results confirm the absence of impurity peaks and the crystal structure change from nanotubes to anatase phase after annealing treatment. The average specific surface area of the particles is probed using gas adsorption-desorption measurements. The prepared tubular samples exhibit greater specific surface areas and higher pore volumes than the precursor. Moreover, it is apparent that the hydrothermal treatment modifies the optical properties of the titania samples and red-shifts the UV absorption to a band gap energy of 3.04 eV after annealing treatment. (C) 2011 Elsevier B. V. All rights reserved.