NiCr + Cr3C2 + Ag + BaF2/CaF2 composite coatings were produced on stainless steel (1Cr18Ni9Ti) substrates by laser cladding. Corresponding powders were prepared by high-energy ball milling technique. The friction and wear behavior at room temperature was investigated through sliding against the Si3N4 ball. The morphologies of the wear debris, worn surfaces of both samples and the Si3N4 ball were analyzed by scanning electron microscopy and three dimensional non-contact surface mapping. Results showed that milling time had a great effect on the size, morphology, uniformity of the powders as well as the microstructure and properties of laser cladding coatings. The wear mechanism of the coatings is dominated by abrasive wear, plastic deformation and slight adhesive wear. The consecutive evolution trend of friction coefficient, wear rate as well as microhardness of the serials of coatings produced with powders of different sizes was presented. (C) 2012 Elsevier B.V. All rights reserved.