Calculating global solar irradiation from global horizontal irradiation only is a difficult task, especially when the time step is small and the data are not averaged. We used an Artificial Neural Network (ANN) to realize this conversion. The ANN is optimized and tested on the basis of five years of solar data; the accuracy of the optimal configuration is around 6% for the RRMSE (relative root mean square error) and around 3.5% for the RMAE (relative mean absolute value) i.e. a better performance than the empirical correlations available in the literature. (c) 2012 Elsevier Ltd. All rights reserved.