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International Journal of Hydrogen Energy, Vol.23, No.12, 1203-1212, 1998
A proton-conducting solid state H2S-O-2 fuel cell. 1. Anode catalysts, and operation at atmospheric pressure and 20-90 degrees C
A stable solid stale H2S-O-2 fuel cell has been developed and operated at 1 atm and 20-90 degrees C. A series of anode catalysts has been examined using Nafion(R) as a common proton conducting membrane; those containing Pd and Pt were found to be effective using H-2 or H2S as the anode feed gas, but MoS2-C catalysts were effective for use of H2S but not for H-2. The highest potential attained using H2S and Pd/C catalyst was 722 mV (theory: 1140 mV). When H2S was used as anode feed the potential decreased up to 35% over 24 h as sulfur was deposited on the anode. The efficiency of the cell increased with temperature up to 90 degrees C.
Keywords:HYDROGEN-SULFIDE;SULFUR