Inorganic Chemistry, Vol.51, No.8, 4423-4425, 2012
Porous Double-Walled Metal Triazolate Framework Based upon a Bifunctional Ligand and a Pentanuclear Zinc Cluster Exhibiting Selective CO2 Uptake
The self-assembly of a custom-designed bifunctional ligand featuring both 1,2,3-triazolate and carboxylate donor groups with a pentanuclear zinc cluster generated in situ affords a double-walled metal triazolate framework (MTAF) material, MTAF-1 (Zn-5(mu(3)-O)(2)(C9N3H5O2)(5)(H+)(4)(H2O)(17)(C3H7NO)(10)), which exhibits a surface area of 2300 m(2)/g and demonstrates interesting selective CO2 uptake performances.