As electrofusion (EF) technology is widely used in connecting polyethylene (PE) pipes and other plastic pipes or composite pipes, research in safety assessment of EF joints has been of major concern. EF joints with defects are very common in practical applications. These defects may greatly reduce the mechanical performance of the EF joints and threat safety running of the pipeline system. To evaluate hazard of these defects and provide a basic understanding for the failure mechanism of EF joints, a comprehensive study on defects and failure modes is conducted in this work. The defects in EF joints are classified into four categories: poor fusion interface, over welding, voids, and structural deformity. The forming reasons of these defects are analyzed in detail. The mechanical properties of EF joint containing these defects are investigated by conducting peeling tests and sustained hydraulic pressure tests. Test results show that there are three main failure mode of EF joint under inner pressure, that is, cracking through the fusion interface, cracking through the fitting, and cracking through copper wire interface. (C) 2011 Wiley Periodicals, Inc. J Appl Polym Sci, 2012