화학공학소재연구정보센터
Bioresource Technology, Vol.99, No.17, 8207-8211, 2008
Electrooxidation as the anaerobic pre-treatment of fats: Oleate conversion using RuO2 and IrO2 based anodes
Electrochemical treatment of oleate using RuO2 and IrO2 type dimensionally stable anode! in alkaline medium was performed to develop a feasible anaerobic pre-treatment of fatty effluents. The results showed that the pre-treated solutions over RuO2 were faster degraded by anaerobic consortium than the raw oleate solutions or the electrolysed solutions using IrO2. In batch experiments carried out with pre-treated solutions over RuO2 (100-500 mg/L), no lag phases were observed before the methane production onset. On the other hand, raw oleate and pre-treated oleate over IrO2 had originated lag phases of 0-140 and 0-210 h, respectively. This study demonstrated that it is advantageous to apply the electrochemical treatment carried out on the RuO2 type DSA in order to achieve a faster biodegradation of lipid-containing effluent and consequently to obtain a faster methane production. (C) 2008 Elsevier Ltd. All rights reserved.