Eucalyprus globulus wood samples were subjected to autohydrolysis for extracting hemicelluloses, and the resulting solids were assayed as substrates for kraft pulping and further Totally Chlorine Free (TCF) bleaching. The susceptibility of treated solids to kraft processing was assessed under selected experiments covering the optimum experimental range. In order to establish a basis for comparison, samples of untreated wood were also subjected to kraft delignification. The best kraft pulps obtained from auto-hydrolyzed solids were subjected to an optimized TCF bleaching sequence involving double alkaline oxygen and pressurized H(2)O(2) processing, and characterized using standard methods. The suitability of the final product obtained by autohydrolysis-kraft delignification-TCF bleaching for specific purposes is discussed on the basis of the experimental results. (C) 2011 Elsevier Ltd. All rights reserved.