An idea of using pure iron and graphite electrodes was employed for synthesizing carbon nanoparticles by arc discharge in liquid nitrogen. The synthesized products consist of multiwalled carbon nanotubes (MW-CNT), carbon nanohorns (CNH), and carbon nanocapsules (CNC) with core-shell structure. Effect of metallic cathode and discharge current on product structure and yield had been experimentally investigated. Typical evidence of transmission electron microscopic images revealed that under some certain conditions of discharge in liquid nitrogen the synthesized products mainly consisted of CNCs with mean diameter of 50-400 nm. When conventional graphitic electrodes were employed, CNHs with some MW-CNTs were mainly synthesized. Meanwhile, MW-CNTs with diameter of 8-25 run and length 150250 nm became less selectively synthesized as cathode deposit under the condition of discharge in liquid nitrogen with higher arc current. The production yield of carbon nanoparticles synthesized by either carbon-carbon or carbon-iron electrodes became also lower with an increase in the arc current. (C) 2008 Elsevier B.V. All rights reserved.