Lead-free (K0.462Na0.48Li0.058)(1+x)NbO3(0 <= x <= 0.03) ceramics with excessive alkaline elements were synthesized by conventional ceramics processes as functions of sintering temperatures and quantities of excess alkaline elements. X-ray diffraction results reveal a transformation from tetragonal phase to orthorhombic phase with increasing the contents of excessive alkaline elements. The grain size and the piezoelectric properties were enhanced when a certain amount of excessive alkaline elements were added. Further elevation in the amount of alkaline elements added resulted in excessive liquid phase in the ceramics and deteriorated the piezoelectric properties. With x = 0.01, the ceramics sintered at 1050 degrees C show better properties of planar electromechanical coupling factor k(p) = 43.4%, piezoelectric constant d(33) = 204 pC/N, dielectric constant epsilon(T)(33)/epsilon(0) = 704: 4, and loss tangent tan delta = 2.8%. (C) 2011 Elsevier B.V. All rights reserved.