Ceramic honeycomb monoliths with a noble metal-alumina based washcoat were used as burners for the combustion of very lean methane-air mixtures below the conventional lower flammability limit without the emission of CO, NOx, or unburned fuel gas. Measurements and modelling in the steady state proved that the near zero emissions could have been equally due to gas phase combustion than to catalytic combustion for the long monoliths. However, only catalytic oxidation reactions could account for the complete and clean combustion observed for the shortest burners, indicating that even in the longest monoliths, the combustion had been catalytic. Thus the onset of gas phase combustion was inhibited by catalytic combustion. This phenomenon was investigated using numerical modelling and experimental studies on a catalytic stagnation point flow reactor, with a polycrystalline Pt foil as the catalyst. These studies showed the extent of the phenomenon of inhibition of gas phase ignition and how catalytic combustion is an extremely stable and clean process.