The thermal stability of mercury captured by ash was studied by sampling ash throughout the collection train of two Kentucky power plants. Sampling occurred over multiple years and involved both fresh and archived samples. During one ash collection episode, sampling was from the combustion of a single pulverized coal feed. The other collections involved ash from blended feeds. Ash was collected from economizer, mechanical and electrostatic precipitator hoppers. Feed coals, rejects and bottom ash were also sampled. Fractions of all the samples were heated in a thermal analyzer to maximum temperatures increased sequentially from 100 to 500 degrees C in 100 degrees C increments. The mercury content of the spent material was then determined by analysis of the solids for Hg. From this data the thermal decomposition temperature of the captured mercury was determined. The total mercury captured by each sample, thermal stability of the mercury in relation to collection site, and correlations between mercury capture and chemical composition of the sample were also determined. The data showed that mercury was released between 300-400 degrees C for all ash samples. The thermal release of Hg between 300400 degrees C was studied in greater detail by following the Hg release in several samples at 25 degrees C intervals from 300-400 degrees C. The concentration of mercury captured in the ESPs hoppers was greater than in the ash collected from the economizer or mechanical separators. (c) 2006 Elsevier Ltd. All rights reserved.